Deviation from Ideal Behaviour

IMPORTANT

Deviation from Ideal Behaviour: Overview

This Topic covers sub-topics such as Difference between Ideal Gases and Real Gases, Compressibility Factor, Real Gas, Deviations from Ideal Gas Behaviour, Compressibility of Gas and, Variation of Compressibility Factor with Pressure

Important Questions on Deviation from Ideal Behaviour

MEDIUM
IMPORTANT

A gas is said to behave like an ideal gas when relation PVT=constant. When do you expect real gas to behave like an ideal gas?

MEDIUM
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Van der Waal’s real gas, act as an ideal gas, at which conditions ?

EASY
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At which one of the following temperature – pressure conditions the deviation of a gas from ideal behaviour is expected to be minimum ?

HARD
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A gas has a compressibility factor of 0.5 and a molar volume of 0.4 dm3 mol-1 at a temperature of 800 K and pressure x atm. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be  y dm3 mol-1 . The value of x/y is _________

[Use: Gas constant, R=8×10-2 L atm K-1 mol-1 ]

HARD
IMPORTANT

A certain quantity of real gas occupies a volume of 0.15 dm3 at 100 atm and 500 K when its compressibility factor is 1.07. Its volume at 300 atm and 300 K (When its compressibility factor is 1.4) is ______×10-4dm3(Nearest integer)

HARD
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A gas at 350 K and 15 bar has molar volume 20 percent smaller than that for an ideal gas under the same conditions. The correct option about the gas and its compressibility factor (Z) is :

HARD
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For which of the following gases, the value of Z is greater than 1 at all pressures and at 273 K?

MEDIUM
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Following data is given for N2
P=800 atm, Z = 1.95, T= 50°C
Calculate the mass (g) of N2 required to fill 500 mL flask under these conditions.
[R=.0821 atm litre mole-1K-1)

HARD
IMPORTANT

Consider the following statements :

I. Density and molar mass of gaseous substance are related as M=dRTp

II. Partial pressure in terms of molefraction is related as pi=χi ptotal

III. At constant temperature, pV vs p plot for real gases is a straight line 

IV. Real gases do not follow ideal gas equation perfectly under all conditions

Choose the correct statements and select the correct option

MEDIUM
IMPORTANT

Gases deviate from ideal behaviour at high pressures because the gas molecules

HARD
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At 300 K and 100 bar pressure, the measured volume of 5 mole of a gas is 2 L. The van der Waals constant b and compressibility factor Z, respectively are

MEDIUM
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Among the gases a, b, c, d, e and f, the gases that show only positive deviation from ideal behavior at all pressures in the graph are

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HARD
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Ideal gas is an imaginary gas but real gas deviate from ideal gas behaviour. How is it possible?

HARD
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In the following isotherms, I (for ideal gas) and II (for real gas), points X and Y on II with respect to I indicate _____ deviation

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EASY
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Select the incorrect statement(s):

MEDIUM
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The internal energy per mole of an ideal gas is denoted by Eideal. The same for a real gas obeying van der Waals equation is Ereal. Assuming the average kinetic energy of the molecules of the two gases at the same temperature to be equal, the correct statement for the gas at low pressure is

EASY
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Regarding H2 gas, the correct statement(s) is/are

EASY
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The correct statement(s) regarding compressibility factor Z is/are